Unless the person you bought the game from gives you his/her Steam account details, you won't be able to use that copy.
Steam has a Total War sale on at the moment, so you can get a working version of the game pretty cheaply - 13.59 USD. But if you don't have the earlier games, you can ETW with them in the
Total War Mega pack for 20.39 USD.
"Into the face of the young man who sat on the terrace of the Hotel Magnifique at Cannes there had crept a look of furtive shame, the shifty, hangdog look which announces that an Englishman is about to talk French." - P.G. Wodehouse, The Luck of the Bodkins